钻井液用液体润滑剂改性植物油（BZ-RH-I）

doi:10.3969/j.issn.1002-302x.2015.z1.006

石油科技论坛 ›› 2015, Vol. 34 ›› Issue (增刊): 21-24.DOI: 10.3969/j.issn.1002-302x.2015.z1.006

钻井液用液体润滑剂改性植物油（BZ-RH-I）

李广环, 黄达全, 苏君, 龙涛, 田增艳, 宋学文, 马红

中国石油集团渤海钻探工程有限公司

收稿日期:2015-07-08 出版日期:2015-10-25 发布日期:2015-11-16
基金资助:
中国石油集团渤海钻探工程有限公司重大专项“强抑制性钻井液体系研究与应用”（编号：2010ZD03K）。

Modified Vegetable Oil Used as Liquid Lubricant for Drilling Fluid BZ-RH-1

Li Guanghan, Huang Daquan, Su Jun, Long Tao, Tian Zengyan, Song Xuewen, Ma Hong

CNPC Bohai Drilling Engineering Company Limited, Tianjin 300280, China

Received:2015-07-08 Online:2015-10-25 Published:2015-11-16
Supported by:

摘要/Abstract

摘要： 以废弃植物油为原料,通过甲酰化、酯化等反应制得一种低凝固点、低荧光的润滑剂BZ-RH-I,并对其合成条件进行了优选和评价。评价结果表明,该润滑剂的荧光级别低于4级,凝固点低于-15℃,加量为钻井液体积0.5%时润滑系数降低率大于90%;在180℃高温老化后,该润滑剂的润滑系数降低率仍然大于85%,具有抗盐、抗温、低荧光、环境友好等特点以及原料来源广泛、合成成本低等优势。经350余口井的现场应用表明,润滑剂能够有效地降低钻井液和钻具间的摩擦阻力,与各种钻井液添加剂配伍性好,减轻了钻机负荷,可满足深井、大位移井、水平井等钻井作业要求。

关键词: 废弃植物油, 低荧光, 低凝固点, 钻井液, 润滑剂

Abstract: With scraped vegetable oil used as raw material, a low freezing-point and low fluorescent lubricant - BZ-RH-1 - is synthesized through formylation, esterification and ester exchange reaction. Based on evaluation of the synthesis conditions, the fluorescence grade of BZ-RH-1 is below Grade 4 and the freezing point is lower than -15°C. Lubrication coefficient reduced rate is higher than 90 percent when added 0.5 percent (volume ratio) in the drilling fluid. After the 180°C high-temperature aging, the lubrication coefficient reduced rate is still higher than 85 percent, showing a series of characteristics, such as salt resistance, temperature resistance, low fluorescence and environmental friendliness. The lubricant has a wide range of sources for raw material and low cost for synthesis. Based on field application of more than 350 wells, the lubricant can effectively reduce friction between drilling fluid and drilling tools with a good compatibility with various drilling fluid additives. It reduces load of drilling rig and meets the demand for drilling service of deep wells, highly-deviated wells and horizontal wells.

Key words: scraped vegetable oil, low fluorescence, low freezing point, drilling fluid, lubricant

中图分类号:

李广环, 黄达全, 苏君, 龙涛, 田增艳, 宋学文, 马红. 钻井液用液体润滑剂改性植物油（BZ-RH-I）[J]. 石油科技论坛, 2015, 34(增刊): 21-24.

Li Guanghan, Huang Daquan, Su Jun, Long Tao, Tian Zengyan, Song Xuewen, Ma Hong. Modified Vegetable Oil Used as Liquid Lubricant for Drilling Fluid BZ-RH-1[J]. Petroleum Science and Technology Forum, 2015, 34(增刊): 21-24.

参考文献

[1] 霍胜军,贾万瑾,张萍,等. 一种新型钻井液用液体润滑剂性能研究[J]. 石油钻采工艺,2007,29(9): 40-46.
Huo Shengjun, Jia Wanjin, Zhang Ping, et al. Research on performance of a new liquid lubricate for drilling fluid[J]. Oil Drilling and Production Technology, 2007, 29(9): 40-46.
[2] 郝宗香,王泽霖,何琳,等. 低荧光水基润滑剂RY-838 的研制与应用[J]. 钻井液与完井液,2012, 29(4): 24-26.
Hao Zongxiang, Wang Zelin, He Lin, et al. Research and application on low fluorescence water-base lubricant RY838[J]. Drilling Fluid and Completion Fluid, 2012, 29(4): 24-26.
[3] 刘维民,许俊,冯大鹏,等. 合成润滑油的研究现状及发展趋势[J]. 摩擦学,2013,33(1):91-104.
Liu Weimin, Xu Jun, Feng Dapeng, et al. The research status and prospect of synthetic lubricating oils[J].Tribology, 2013, 33(1):91-104.
[4] 吕开河,陈亚男,张佳,等. 钻井液用防塌润滑剂研究与应用[J]. 海洋石油,2011,31(3): 78-80.
Lv Kaihe, Chen Yanan, Zhang Jia, et al. Application and research of anti-sloughing lubricant for drilling fluids[J]. Offshore Oil, 2011, 31(3): 78-80.
[5] 孙金声,潘小镑,刘进京. 新型钻井液用润滑剂GXRH的研制[J]. 钻井液与完井液,2002,19 (6): 13-14.
Sun Jinsheng, Pan xiaobang, Liu Jinjing. Development of a novel drilling fluid lubricant GXRH [J]. Drilling Fluid and Completion Fluid, 2002, 19 (6 ): 13-14.
[6] 王宁,胡萍,袁继勇,等. 以菜籽油为基础油的绿色润滑剂制备[J]. 武汉工程大学学报,2012,34 (3) : 15-17.
Wang Ning, Hu Ping, Yuan Jiyong, et al. Preparation of green lubricants used rapeseed oil as base oil[J]. J. Wuhan Inst. Tech., 2012, 34 (3) : 15-17.
[7] 郭瑞华. 棕榈油制备润滑剂的研究[D]. 郑州:河南工业大学学位论文,2010.
Guo Ruihua. Preparation of palm oil lubricant[D]. Zhengzhou: Henan University of Technology, 2010.
[8] 孙金声,张希文. 钻井液技术的现状、挑战、需求与发展趋势[J]. 钻井液与完井液,2011,28(6):67-76.
Sun Jinsheng, Zhang Xiwen. Situations, challenges, demands and trends of drilling fluid technology[J]. Drilling Fluid and Completion Fluid, 2011,28(6):67-76.
[9] 蔡利山.钻井液技术发展趋势[J].石油科技论坛,2014, 33(1):15-20.
Cai Lishan. Trend for development of drilling fluid technology[J].Oil Forum,2014,33(1):15-20.

[1]	张现斌　赵　冲　王伟忠　张向明　龚纯武　黄　杰　刘　国　孙　双. BH-OBM 油基钻井液体系研究与应用[J]. 石油科技论坛, 2017, 36(增刊): 30-33.
[2]	尹志亮　李　燕. 油基钻井液用有机土产业化、规模化研究与应用[J]. 石油科技论坛, 2017, 36(增刊): 41-44.
[3]	凡　帆　王京光　赵海峰. CQ-HDEM 无土相油基钻井液技术[J]. 石油科技论坛, 2017, 36(增刊): 45-47.
[4]	李东杰　王　炎　魏玉皓　张　彬　于建涛　张　波　廖沫然. 页岩气钻井技术新进展[J]. 石油科技论坛, 2017, 36(1): 49-56.
[5]	王　臣　李志刚. 钻井液循环管汇[J]. 石油科技论坛, 2016, 35(增刊): 61-63.
[6]	屈沅治　黄宏军　卢凤珍. 胺基钻井液体系DRABM[J]. 石油科技论坛, 2016, 35(增刊): 82-84.
[7]	黎金明, 陈磊, 蔺文洁, 张振活. CQ-BOL生物油润滑剂[J]. 石油科技论坛, 2015, 34(增刊): 25-27.
[8]	王建华, 王立辉, 杨海军, 闫丽丽, 李龙. 抗高温高密度油基钻井液体系DR-OBM[J]. 石油科技论坛, 2015, 34(增刊): 56-58.
[9]	邸伟娜,赵汩凡,李婧,王敏生. M-I SWACO公司控制井壁稳定钻井液技术专利分析[J]. 石油科技论坛, 2014, 33(5): 69-73.
[10]	蔡利山. 钻井液技术发展趋势[J]. 石油科技论坛, 2014, 33(1): 15-20.
[11]	汪海阁,刘岩生,王灵碧. 国外钻、完井技术新进展与发展趋势(Ⅰ)[J]. 石油科技论坛, 2013, 32(5): 36-42.
[12]	刘梅全, 杨庆理, 郑毅. 倾力打造钻井液技术服务利器确保钻井施工安全快速高效——中国石油钻井液技术发展评述[J]. 石油科技论坛, 2012, 31(3): 6-9,13.
[13]	许锦华, 柴占文, 刘维彬, 胡小刚, 侯召坡. 圆形罐钻井液固控系统[J]. 石油科技论坛, 2012, 31(3): 58-59.
[14]	王卫国, 刘梅全, 艾贵成, 乔国文, 盖靖安, 张宝峰. 无固相钻井完井液的研究与应用[J]. 石油科技论坛, 2012, 31(2): 36-39.
[15]	宋洵成, 王振飞, 徐小龙, 胡莎莎. 大位移井岩屑床危害及处理措施研究[J]. 石油科技论坛, 2012, 31(2): 40-42,52.

钻井液用液体润滑剂改性植物油（BZ-RH-I）

Modified Vegetable Oil Used as Liquid Lubricant for Drilling Fluid BZ-RH-1

PDF

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics